- What does CVD stand for in diamonds?
- What is CVD?
- What is CVD diamond?
- How are CVD diamonds made?
- Are they Artificial Diamonds?
- What is the Resale Value of Lab Grown Diamonds?
- Why is it difficult to synthesize diamond?
- How does CVD work?
- What gasses are used for CVD DIAMONDS?
- What are approx growth temperatures required for CVD Diamonds?
- How fast Grows does CVD DIAMOND?
- What substrate material can be used to make CVD DIAMONDS?
- What are the typical grain sizes of the polycrystalline diamond?
- What is the nano-crystalline diamond?
- What is the surface roughness?
- How does CVD diamond compare to DLC?
- How do CVD diamond compare to natural diamond?
- Is CVD diamond expensive?
- Is CVD diamond a billion market?
- Where can I find a collection of the properties of CVD diamond?
- Where can I buy/purchase CVD diamond?
CVD means Chemical Vapor Deposition. CVD produces Colorless synthetic diamonds which are becoming more common in the market.
CVD-processed stones are vastly different from the natural diamonds produced by geologic forces. They are also very much different from the High Pressure, High Temperature (HPHT) CVD diamonds that have been manufactured since the mid-1950s.
The HPHT technique initially used to successfully develop diamonds by General Electric in 1954, basically copies the common procedure – carbon is crystallized as diamond through intense heat and pressure deep within the Earth. The HPHT process is very costly, given the energy and equipment required, and produces diamonds with mainly yellowish or brownish-yellow colors.
CVD diamonds began appearing in the gem diamond market about a decade ago. The process involves introducing a gas, such as methane, into a vacuum chamber, then activating and breaking down the molecules of the gas with microwaves. This causes the carbon atoms to accumulate on a substrate (a small platform containing a flat diamond seed crystal, usually an HPHT synthetic), similar to the way snowflakes accumulate in a snowfall.
The CVD method is much less costly because it works at moderate temperatures and low pressure, which requires smaller and less expensive equipment. Since the vacuum chamber contains just carbon and some hydrogen, colorless crystals can be develope If nitrogen or boron is introduced into the chamber, yellow or blue CVD diamond crystals can be produced.
In the past decade, CVD producers have found that changing the gases in the development chamber and utilizing a purer Type II CVD diamond as a seed crystal can enhance the shade of the finished synthetic diamond and speed the development rates. Since many early CVDs had a brownish color, producers also found that treating the material at high temperatures and pressures can remove the brown coloration to make the crystals colorless. This treatment step masked some of the signature features, which resulted in the identification of these synthetic diamonds becoming more difficult.
At first, the creators of these CVD diamonds thought they would be able to produce diamonds quickly and cheaply. However, because the quality was inconsistent and the typical brown colors were less than desirable, those expectations were not met.
The Genesis Corporation of Sarasota, Florida, which produced its earlier CVD diamonds with the HPHT-process, began to market colorless CVD diamonds in March 2012. There are several other companies which also sell CVDs.
GIA researchers purchased 16 CVD diamonds from Gemesis, 15 of them cut into round brilliants, ranging from 0.24 carats to 0.86 carats. The majority had very high colors, ranging F-G on the GIA 4Cs scale. Three were I-J. The largest, at 0.90 carats, was a rectangle cut graded L, since it showed a slight yellowish cast.
The GIA tests found that the quality of colorless to near-colorless CVD-grown diamonds has improved significantly in the decade since they were introduced. In the past, CVD diamond displayed graining patterns not found in natural diamonds, as well as distinctive fluorescence reactions. These samples showed that separating such stones from natural diamonds requires the use of advanced spectroscopic techniques. In addition, it was apparent that the cvd diamond were treated under high heat to remove or obscure some of their telltale features, such as graining which, after treatment, is very difficult to see.
The researchers, led by Dr. Wuyi Wang, GIA’s director of research and development, subjected these CVD diamonds to an extensive battery of tests. The tests included several sophisticated types of spectral analysis to obtain a telltale “signature” of samples created by the CVD process. By using advanced instrumentation, scientists can read the diamonds’ spectral signature to determine their composition, or whether they originated in nature or a laboratory. The GIA researchers also conducted standard gemological tests, including checking for features known to be diagnostic for other CVD diamonds, such as graining patterns and ultraviolet fluorescence reactions. Diamonds have a grain, like wood, that is a result of the way they crystallize, but because they grow differently in nature than in a lab, the grain patterns of CVD diamonds are different.
Despite the difficulty in spotting these stones by conventional means, GIA researchers did find unique spectroscopic signatures. They did so by subjecting photoluminescence and ultraviolet fluorescence reactions to the Diamond View, a sophisticated instrument used by gemological labs to detect CVD diamonds.